WISE
187 - Spring 1999
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Introduction:
The Earth's interior is able to be studied in
various ways. Xenoliths provide a source of direct information by providing
scientists with rock samples from the Earth's interior. The study of
seismology is a direct but inferred process which provides interpretations of
vibrations that pass through the Earth's interior. An indirect method for the study is by
performing high pressure and high temperature laboratory experiments. In our
experiment, we attempted to turn graphite into diamonds using high pressure equipment.
Diamonds are metastable at atmospheric pressure therefore we tried to imitate the
conditions in which diamonds form. We created a high pressure and high temperature
environment, similar to that found in the upper mantle. The temperature
necessary for diamonds to form is at least 1,350 degrees Centigrade and the pressure
is 57,000 times that of the atmosphere. It took approximately an hour to prepare the
sample. The high pressure and high temperature process lasted for five hours but the
actual period for the formation of diamonds was only fifteen minutes.
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SETUP:
Curious about
how we made diamonds? This is how we synthesized them. We took eight tungsten cubes and
separated them with balsa wood and gaskets. This provided a cozy hole (tetrahedron) in the
center, where the sample was placed. The sample was composed of three graphite disks
sandwiched in four layers of a nickel-manganese powder catalyst. The eight cubes were kept
intact by laminated plastic squares. There were copper electrodes placed between the
plastic and cubes number three and eight. The electrodes provided an electric current that
heated the sample. The entire assembly was placed in the Kennedy Press and slowly raised
to an ideal pressure of 57 kilobars over the duration of five hours. When this pressure
was reached, the temperature rapidly increased to 13500 C. After the ideal
conditions were met, we were able to create diamonds in fifteen minutes!!
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Results:
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Our experiment was successful. We waited in anticipation as the last pieces of plastic were removed from the tungsten carbide cubes. The cubes were taken apart, and the octahedron that was holding the diamonds was broken into small pieces. Inside, there were some particles that we could not immediately determine to be diamond by simply examining them. In order to determine the presence of diamonds, we performed the following tests. We attempted to scratch a cube of tungsten carbide with some of the small diamonds. Since diamond is hardest substance known to man, it should have been able to scratch tungsten carbide, a very hard substance. Through careful observation with a microscope, we were able to detect trace amounts of diamonds. In addition, we were able to observe the scratches on the tungsten carbide cube. There are several substances harder than tungsten carbide, but the materials that make up these substances were not used. Therefore, scratches present must have been caused by diamond. Overall, creating diamonds was a fun and exciting process.